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http://148.72.244.84/xmlui/handle/xmlui/13005| Title: | The Manufacture of Perchlorate by Direct Method Using Graphite Substrate Lead Dioxide (Gsld) Anode |
| Authors: | Ahmed D. Wiheeb |
| Keywords: | Perchlorate, Lead Dioxide Anode, GSLD Anode, Direct Oxidation Of Sodium Chloride |
| Issue Date: | 1-Jun-2009 |
| Publisher: | University of Diyala – College of Engineering |
| Citation: | https://djes.info/index.php/djes/article/view/701 |
| Abstract: | Sodium perchlorate has been prepared electrochemically from sodium chloride solutions in one step by passing a direct current through the solution , in the presence of certain addition agents (like sodium fluoride). A laboratory electrolytic cell has been designed to obtain experimental results for the preparation of sodium perchlorate. A solution of sodium chloride (290 g/l ) and sodium fluoride (2 g/l ) is electrolyzed in a batch wise. A stainless steel cathode and Graphite substrate lead dioxide (GSLD) anode are satisfactory . The influence of anodic current density , temperature ,and pH of electrolyte on current efficiency of sodium perchlorate formation were studied. The current efficiency of about 68% was obtained by using (GSLD) anode |
| URI: | http://148.72.244.84:8080/xmlui/handle/xmlui/13005 |
| ISSN: | 1999-8716 |
| Appears in Collections: | مجلة ديالى للعلوم الهندسية / Diyala Journal of Engineering Sciences (DJES) |
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